Polymer/glass hybrid coating

ABSTRACT

A 1 to 8 micron organic/inorganic (epoxy/glass) wear surface coating over a clear, protective layer provides excellent stain and gloss protection. An acid hydrolyzed silicate is combined with an acid hydrolyzed silicone coupling agent; an epoxy monomer; a photoinitiator and silicon oil surfactant to produce a coating composition which is dried to remove alcohol/water solvent and U.V. cured.

CROSS-REFERENCE TO RELATED PATENT

This is a continuation of Ser. No. 209,097, filed Jun. 20, 1988, now U.S. Pat. No. 5,023,140, issued Jun. 11, 1991.

FIELD OF THE INVENTION

The present invention relates to coating compositions. More particularly, the invention relates to a novel epoxy/glass coating composition which provides stain and gloss protection when applied over a clear, protective layer.

BACKGROUND OF THE INVENTION

From the mid-1940's it was known that metal alkoxide could be hydrolyzed and condensed to form glasses. Subsequently, from about the mid-1970's it was known that silica could be produced in situ as a chemical product of compounds such as tetraethylorthosilicate (TEOS).

It was previously known from U.S. Pat. No. 3,811,918, to partially acid hydrolyze silicon alkoxide and add metal oxide to prepare a glass precursor which could be fired to a glass composition at a temperature above 1000° C. Further, U.S. Pat. No. 4,346,131 describes the preparation of a clear alcohol solution of acid hydrolyzed metal alkoxide which can be coated on a substrate and dried to produce an optical coating.

Silane coupling agents as disclosed in U.S. Pat. No. 4,480,072 provided a useful means to crosslink organic and inorganic surfaces and particles.

An article on SOL-GEL DERIVED DIP COATINGS by Helmut Dislich of Schott Glaswerke, Hattenbergstr. 10, 6500 Mainz, Federal Republic of Germany, discloses how mixtures of metal alkoxides may be used to condense mixed metal on a glass surface such as silicon-titanium, aluminum-magnesium, cadmium-tin, indium-tin, etc. An article on ORGANICALLY MODIFIED SILICATES AS INORGANIC-ORGANIC POLYMERS by H. K. Schmidt of Fraunhofer-Institut fur Silicatforschung, Wurzburg, Federal Republic of Germany, describes combinations of linear organic polymer networks with three dimensional tetrahedron silicon networks using the sol-gel process, e.g. where combined polymerization of methacrylate and condensation of Ti(OR)₄ /Si(OR)₄ /epoxy-Si(OR)₃ produce a reinforced system with increased tensile strength and scratch resistance.

Japanese Application 86/25,739 discloses antifogging tile coatings where silica is bonded to polyvinyl alcohol using hydrolyzed [3-(glycidyloxy)propyl] trimethoxysilane.

European Patent Application 222,582 discloses an ultraviolet curable composition with good adhesion to glass comprising epoxy resin, poly-organosiloxane, aromatic onium salt and acrylate resin.

British Patent Application GB 2,177,093 covers an ultraviolet curable coating composition comprising multifunctional glycidyl or cycloaliphatic epoxy oligomer, hydrolyzed silane coupling agent treated inorganic filler and photoinitiator for reaction of epoxy groups.

Still, in spite of all the known art and available compositions of matter, a need existed to provide protective wear surfaces which could be conveniently produced without adverse environmental effects.

SUMMARY OF THE INVENTION

A protective coating composition having improved stain resistance and gloss retention suitable for coating wear surfaces comprises

(a) an acid hydrolyzed silicate;

(b) an acid hydrolzed epoxy/silane coupling agent;

(c) a difunctional monomer; and

(d) a photoinitiator.

A preferred composition comprises

(a) about 10 to about 70% of an acid-catalyzed hydrolysis product of at least one silicate selected from the group of tetramethylorthosilicate (TMOS), tetraethylorthosilicate (TEOS) or tetrapropylorthosilicate (TPOS);

(b) about 1 to about 70% acid-catalyzed epoxy/silane coupling agent;

(c) about 1 to about 70% of an difunctional, cycloaliphatic epoxy monomer having at least one cyclohexene oxide functionality;

(d) about 0.5 to about 10% of an photoinitiator capable of initiating ring-opening, cationic photopolymerization of (c); and

(e) about 0.1 to about 1% of an poly(dimethylsiloxane) surfactant, wherein the cured coating has a MOHS' hardness greater than 1.5.

A method for preparing a protective coating comprises

(a) combining acid hydrolyzed solutions of

(i) a metal alkoxide solution having a pH of about 4 or less;

(ii) an epoxy/silane coupling agent solution having a pH of about 4 or less;

(b) adding a difunctional cycloaliphatic epoxy monomer to the hydrolyzed solution;

(c) applying the composition in a thickness ranging between about 1 and about 8 microns over a clear, protective layer bonded to a substrate;

(d) drying the composition to remove solvent; and

(e) curing the composition.

Preferably, the protective layer is bonded to a substrate comprising tile, flooring, table top, counter, panel, or similar article of manufacture. Clear, protective layers are standard in these industries, but polyester, polyacrylate, and acrylated urethane types have been found to be particularly suitable.

The coating may be cured by any suitable means including heat or ultraviolet light irradiation.

DETAILED DESCRIPTION OF THE INVENTION

The hardness and durability of ceramics has long made them a desirable surface for both wall and floor applications. The best ceramics have MOHS hardness ratings of 8 and above. Unfortunately, all traditional ceramics with high MOHS hardnesses require, as part of their processing, a firing step during which temperatures of 800° C. and above are the norm. To create a ceramic surface on a typical floor substrate such as vinyl tile, then, would seem to be highly improbable.

Yet in spite of the difficulty perceived, the present invention provides a polymer/glass hybrid coating based on sol-gel technology that has outstanding physical properties, for example, on vinyl-based flooring substrates.

The sol-gel process embodies the phase transformation of a colloidal dispersion (or sol) of a metal oxide to a gel. The metal oxide gel can then be dried to form the corresponding glass as indicated by Formula (1) ##STR1## where X=Si, Ti, Al . . .

Methods of accomplishing the sol-gel transformation include: dispersion of a fine particulate metal oxide (e.g. silica) in an aqueous acidic solution, neutralization of an acidic metal salt solution (e.g. indium nitrate in nitric acid), neutralization of an alkali metal silicate with acid (e.g. sodium silicate), and the hydrolysis/condensation reaction of a metal alkoxide or halide (e.g. tetraethylorthosilicate or tetrachlorosilane).

Sol-gel processing of metal alkoxides is of particular importance because with varying reaction conditions the control of particle size in gels is possible (optical clarity), the composition of the final glass can be easily varied (toughened glasses e.g. borosilicate, zirconia/silica), and polymer species can be introduced in solution to achieve hybrid inorganic/organic materials.

Generally, any of the metal alkoxides based upon Al, Zr, Si, or Ti will readily form oxides after hydrolysis and removal of solvent as indicated by Formula (2) ##STR2## where X=Si, Ti, Zr, Al . . .

Typically, the hydrolysis/condensation reactions of metal alkoxides are run using a stoichiometric amount of water and at a pH of about 2. This procedure works well for the silicon and aluminum alkoxides but other alkoxides such as zirconium and titanium require a very low pH or slow hydrolysis reactions to maintain a reasonable stability. Those alkoxides forming stable gels at low pH are otherwise unsuitable for inorganic/organic hybrid systems due to the reactivity of the monomer/polymer portion of the system.

Many alkoxides, when hydrolyzed, immediately condense to form macroscopic metal oxide particles. Zirconium and titanium alkoxides exhibit this behavior if the pH of the system is not sufficiently low. Silicon and aluminum alkoxides, however, are able to be hydrolyzed at pH's of 2-5 and remain stable for relatively long periods of time.

The term polymerization is often used in sol-gel processing to describe the transformation of the sol phase to the gel/glass phase since glass is a polymer. However, it is probably more correct to think of the gel-to-glass conversion as an aggregation step during which discrete oxide particles of small size (in the range of 4 nm for acid catalyzed silicon alkoxides) form and are chemically bonded to one another. This contrasts with the molecular polymerization concept where each functional group is reacted to form either a linear or three dimensional network.

Glasses prepared from acid-catalyzed sol-gel processes form clear, hard films due to the extremely small sizes of the aggregated oxide particles and in thin films (150 nm), sol-gel derived glasses can rival the performance of traditional glasses. Silicon alkoxides are by far the easiest alkoxides from which such glasses can be formed. Using metal halides has the disadvantage of acid generation during the hydrolysis step. Alkoxides such as tetraethylorthosilicate (TEOS) and tetramethylorthosilicate (TMOS) are readily hydrolyzed at pH 2 and condense upon evaporation of solvent to give approximately 90% yield pure silica as determined by IR (powder dried 2 hrs. @ 150° C.). If the hydrolysis product is left in solution and the solution sufficiently concentrated, a gel will form in 24-72 hours.

The present invention provides a hybrid coating based on a cycloaliphatic epoxy and a silicon alkoxide. Typically, the coatings have a MOHS hardness rating of 1.5-4. While falling short of the MOHS hardness of ceramic surfaces, the hybrid coating represents an increase in hardness compared to normal "hard" polymers (e.g. PMMA has a MOHS hardness of 1.50). In fact, it has been a surprising result to find that 0.5 to 8 micron coatings of the present invention have stain resistance and wear retention rivaling ceramic tile. Thus, when applied to a flooring structure consisting of either a tile or resilient base and an intermediate layer of a U.V. curable clear, transparent layer, a 1-2 micron coating of the invention greatly enhances the wear properties of currently available flooring wear surfaces when applied via a spray or dip process.

The general scheme for producing a polymer/glass hybrid is: (1) preparation of a hydrolyzed metal alkoxide in solution (acid catalyzed), (2) preparation of a hydrolyzed coupling agent (i.e. bifunctional having one trialkoxysilane functionality and one organic functionality) in solution (acid catalyzed), and after mixing the above, (3) inclusion of a photopolymerizable monomer (either free-radical or cationically initiated, (4) inclusion of an appropriate photoinitiator, (5) inclusion of a surfactant, (6) coating on a clear, protective layer (7) drying, and (8) ultraviolet exposure.

Tetramethylorthosilicate (TMOS), tetraethylorthosilicate (TEOS) and tetrapropylorthosilicate (TPOS) are the preferred silicates for acid hydrolysis at a pH of 4 or below. Triethylborate (TEB) or boric acid may be substituted for the TMOS, TEOS or TPOS in amounts from 0.25 to 1.5% by weight of TMOS, TEOS or TPOS in order to increase the useful lifetime of the coating solution. While other metal alkoxides might not be as convenient to use, they nevertheless could be employed to vary the properties of the wear surface protective coating within the practice of the present invention as long as they are compatible with the sol-gel process.

There are a number of commercially available silane coupling agents with polymerizable functional groups. Acrylates, methacrylates and epoxides which contain silanes are available as silane coupling agents.

Epoxy functional coupling agents perform best when they incorporate a trifunctional alkoxysilane. While it is not critical if the epoxy silane is either a glycidyl ether or cycloaliphatic oxide type, a preferred coupling agent is 3-glycidoxypropyltrimethoxy silane.

Epoxy monomers which were found to be useful within the present invention include:

    ______________________________________                                                 Manu-                     Trade Name                                   Epoxy   facturer  Chemical Name   Equivalents                                  ______________________________________                                         ERL-4221                                                                               Union     3,4-epoxycyclohexyl-                                                                           CY-179                                               Carb.     3,4-epoxycyclohexane                                                                           (Ciba-Geigy)                                                   carboxylate                                                  ERL-4299                                                                               Union     Bis(3,4-epoxy-6-methyl                                                                         CY-178                                               Carb.     cyclohexyl) adipate                                                                            (Ciba-Geigy)                                 ERL-4201                                                                               Union     3,4-epoxy-6-methyl                                                                             --                                                   Carb.     cyclohexanmethyl-3,4-                                                          epoxy-6-methyl                                                                 cyclohexane carboxylate                                      ERL-4206                                                                               Union     Vinylcyclohexenedioxide                                                                        RD-4                                                 Carb.                     (Ciba-Geigy)                                 DECO    Aldrich   1,2,5,6-diepoyx --                                                             cyclooctane                                                  ______________________________________                                    

On the other hand, epoxy monomers which were found to be incompatible with the present invention include:

    ______________________________________                                         MK-107   Wilmington   Cyclohexenedimethanol                                             Chemical     diglycidyl ether                                         Heloxy 68                                                                               Wilmington   Neopentyl glycol diglycidyl                                       Chemical     ether                                                    DER 831  Dow Chemical Diglycidyl ether of                                                            bisphenol A                                              DEN 438  Dow Chemical Polygllycidyl ether of                                                         phenol-formaldehyde novolac                              EPN 1139 Ciba-Geigy   Novolac                                                  ______________________________________                                    

While it is not known with any degree of certainty, it is believed that cycloaliphatic oxide functionality must predominate over glycidyl ether functionality in order for the epoxy monomer to produce the hybrid system of the present invention.

A particularly useful epoxide is ERL-4221 available from Union Carbide with the structural formula: ##STR3##

It has been discovered that a vinyl monomer such as triethylene glycol divinyl ether can also provide excellent gloss protection and stain resistance equivalent to the preferred epoxy monomers.

Acrylate or vinyl monomers such as described in U.S. Pat. Nos. 2,760,863; 2,791,504; 2,927,022; 3,261,686; or 3,380,831 may be employed solely or in combination with epoxy monomers depending on the degree of hardness desired for the protective coating. Mixtures of monomers may necessitate having mixtures of photoinitiators for both types of polymerization. For epoxy polymerization there are commercially available photoinitiators which produce an acid catalyst capable of initiating epoxy polymerization based on aryliodonium, arylsulfonium or aryldiazonium compounds. These include diphenyliodonium hexafluorophosphate and bis[4-(diphenylsulfonio)-phenyl]sulfide-bis-hexafluorophosphate.

A surfactant can be conveniently employed in the coating composition. Suitable surfactants include: Triton® X-100 from Rohm and Haas, Surfynol 104-E from Air Products, Aerosol OT from American Cyanamid, FC-120 from 3M, and Tergitol NP-27 from Union Carbide. It is preferred to use a silicone oil surfactant such as poly(dimethylsiloxane) to obtain superior stain and gloss protection.

The hard, epoxy/glass (inorganic/organic) coating composition is prepared by combining the acid-catalyzed hydrolysis product of either tetramethylorthosilicate (TMOS), tetraethylorthosilicate (TEOS) or tetrapropylorthosilicate (TPOS) with the acid-catalyzed hydrolysis product of an epoxy/silane coupling agent such as 3-glycidoxypropyltrimethoxysilane or 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane. The hydrolysis of the alkoxide and the coupling agent are carried out with stoichiometric amounts of 0.1% aqueous HCl solution. The liquor from the hydrolysis reaction is combined with a difunctional epoxy resin having at least one cycloaliphatic epoxide functionality such as 4-vinyl cyclohexenedioxide or an epoxy resin such as 3,4-epoxy-cyclohexylmethyl-3,4-epoxy cyclohexane carboxylate. An amount of arylonium salt capable of initiating the ring-opening, cationic photopolymerization of the epoxy resin is used as well as 0.25 weight percent of a surfactant based on poly(dimethylsiloxane). The combined ingredients are coated via a blade applicator, spray, or flood coating onto a substrate and dried to a slight tack state, U.V. cured using a dosage of typically 1.0-3.0 joules/cm², and in an optional step, heat cured at 250° F.

Generally the more basic the hydrolysis reaction, the larger the particle size in the aggregated gel that forms. When the particles reach sufficient size, they interfere with visible light and form opaque gels. If the pH of the reaction mixture is >7 the most likely result is a precipitated silica product. The gels are of high clarity and have the physical characteristic of behaving as though in a highly compressed, totally elastic state much like a "superball". The gel continues to densify with the evaporation of solvent until eventually reaching a glass state. Sol-gel processing of metal alkoxides is highly sensitive to stoichiometric factors during hydrolysis as well as the pH of the medium in which the hydrolysis condensation reaction is carried out.

Although the sol-gel process provides a route for the low-temperature conversion of metal alkoxides to glasses, the problems encountered during the drying stage after gel formation are formidable (volume changes of 8:1 are common). And although the sol-gel process is touted as a low-temperature route to glass formation, the temperatures involved in transforming gels to glasses are almost always much higher than practical for a wear surface production process. Polymer/glass hybrids, however, can be designed to obtain their ultimate properties at suitable temperatures. It has been discovered that silica/epoxy hybrids can be processed at temperatures ranging from 125° to 400° F. Generally, the higher the processing temperature, the harder the final wear surface obtained.

Formulations particularly useful for the present invention contain four essential elements: (1) acid hydrolyzed silicon alkoxide, (2) acid hydrolyzed silicon alkoxide coupling agent, (3) difunctional, cycloaliphatic epoxy monomer, and (4) silicone surfactant. Total water content for the coating formulation is typically about 20% by weight. A coating is prepared from the formulation by any thin film application method, dried and exposed to U.V. or electron beam radiation. The resulting hybrid film consists of a chemically bonded glass phase and polymer phase as typified by the following reactions: ##STR4## where R=epoxy, acrylate . . . and a=multifunctional polymerizable monomer (epoxy, acrylate . . . )

Polymer/glass hybrids have advantages over all glass systems in that they can be applied as relatively thick coatings (3-5 mils), require modest cure energy, and exhibit outstanding performance as wear surfaces in flooring applications. Coating thicknesses of 1-2 microns have proven to be especially outstanding in physical property tests when applied over flooring substrates.

INDUSTRIAL APPLICABILITY

The present invention advances building and flooring materials art by providing a hard wear surface with excellent stain and gloss protection which can be bonded over a relatively soft surface. Since these transparent polymer/glass (organic/inorganic) compositions can be applied over clear, protective layers, there can be a wide range of applications for a wear surface which will not detract from the appearance of the support or surface being protected.

The following examples illustrate the practice of the present invention.

PREPARATION AND TEST PROCEDURES

For safety considerations all preparatory work should be done in a hood. The tetraethylorthosilicate (TEOS) hydrolysis is carried out using a stoichiometric amount of water and is catalyzed by keeping the pH of the reaction mixture at about 2 (normally 1 or 2 drops conc. HCl in a batch size using 100 ml. TEOS). The coupling agent hydrolysis is carried out separately and also uses a stoichiometric amount of water (one drop conc. HCl catalyst per 50 ml. batch size). There is an exotherm observed in both hydrolysis reactions. After the hydrolysis reactions are completed, the coupling agent and TEOS solutions are stirred for at least 30 minutes. After this time, the two solutions are combined in a two to one weight ratio of TEOS solution to coupling agent solution. The epoxy and epoxy photoinitiator are added. The solution is mixed well for 15 minutes and is then ready for coating after addition of the silicon oil surfactant. If dilutions are to be made, they are done at this point with an 80/20 volume percent mixture of ethanol and water.

For test purposes, a tile or resilient substrate having a typical filled or unfilled PVC plastisol composition was prepared by applying a U.V. curable, clear, protective coating, usually via a curtain-coater, at a thickness of 2-4 mils and cured via a dosage of 3 joules/cm² U.V. The coated flooring structure was then given a spray or dip application of the invention sufficient to give a 1-2 micron dry thickness of the invention and subsequently exposed to U.V. radiation.

Stain protection was determined by comparing discoloration of control and invention test samples which were covered with various stain compositions and then wiped clean.

Trafficked samples were abraded with dirt for 30, 60 and 90 minutes and comparative gloss measurements were taken to determine the effectiveness of the protective surface. The % reduction from the initial gloss reading can be taken as an indication of surface wear.

EXAMPLE 1

    ______________________________________                                         Tetraethylorthosilicate (TEOS)                                                                             93.4 g                                             3-glycidoxypropyltrimethoxysilane (GPTMOS)                                                                 55.0 g                                             ERL-4221 Epoxy Monomer      10.0 g                                             FX-512 photoinitiator       0.6 g                                              Water (Acidified w 0.19% con. HCl)                                                                         46.0 g                                             Ethyl Alcohol (abs.)        100 (ml.)                                          Poly(dimethylsiloxane)      0.395 g                                            ______________________________________                                    

The ingredients designated ERL-4221 and FX-512 are tradenames for the difunctional, cycloaliphatic epoxy monomer and arylonium salt and are marketed by Union Carbide and 3M Company, respectively.

The TEOS and 32.5 g water were combined in a beaker and let stir for 45 minutes. During this time, the GPTMOS was combined with 13.5 g water and stirred. After 45 minutes (or when the TEOS solution was clear), the TEOS and GPTMOS solutions were mixed and the remaining components were added as described above.

A coating of 1-2 micron final thickness was obtained by a 4:1 dilution with an 80/20 volume percent mixture of ethyl alcohol (abs.) and water followed by the spray application of approximately 1 mil wet of the diluted form of Example 1. After 5 minutes at 150° F. drying time, the coating was U.V. cured with a dose of 3 joules/cm².

Table 1 and Table 2 contain comparative results for stain and gloss protection for the invention versus uncoated control tile.

                  TABLE 1                                                          ______________________________________                                                   30 Min.      60 Min.  90 Min.                                        Test      % Gloss      % Gloss  % Gloss                                        Sample    Retained     Retained Retained                                       ______________________________________                                         Control    89           71      38                                             Invention 100          100      94                                             ______________________________________                                    

                  TABLE 2                                                          ______________________________________                                         Stain After Wiping                                                             Test Stain    Invention      Control                                           ______________________________________                                         Blue Marker   None           None                                              Shoe Polish   None           Severe                                            Ink           None           Moderate                                          Hair Dye      None           Severe                                            Iodine        None           Severe                                            Driveway Sealer                                                                              None           Slight                                            ______________________________________                                    

EXAMPLE 2

A formulation was prepared as in Example 1 except that 4-vinyl cyclohexene dioxide was used as the epoxy monomer and diphenyliodonium hexafluorophosphate was used as the photoinitiator. After U.V. exposure and heat curing at 250° F. for 30 minutes, a clear, hard, abrasive-resistant coating was produced which had excellent resistance to household stains similar to Table 2.

EXAMPLE 3

Coatings were prepared as in Example 1 except that tetramethylorthosilicate (TMOS) or tetrapropylorthosilicate (TPOS) were used to replace TEOS as the acid hydrolyzed silicate. After U.V. curing, the samples were heat cured at 250° F. for 30 minutes. These samples gave moderate stain versus severe stain for the control.

EXAMPLE 4

Coatings were prepared as in Example 1 except that a cycloaliphatic epoxy/silane coupling agent was used. The coupling agent, 2-(3,4-epoxycyclohexyl) ethyl-trimethoxysilane, gave satisfactory coating compositions and was U.V. cured to produce satisfactory wear surfaces with properties similar to Tables 1 and 2 above.

EXAMPLE 5

A composition containing acrylate monomer was prepared as follows:

    ______________________________________                                         Ingredient            Amount (g.)                                              ______________________________________                                         Tetraethylorthosilicate (TEOS)                                                                       2.5                                                      Hydroxypropylacrylate 3.1                                                      Methacryloxypropyltrimethoxysilane                                                                   2.5                                                      Pentaerythritoltriacrylate                                                                           10                                                       Acidified Water (0.1% HCl)                                                                           1.8                                                      Benzophenone          0.15                                                     2,2-dimethoxy-2-phenylacetophenone                                                                   0.15                                                     DC-193 PDMS Surfactant                                                                               1 drop                                                   ______________________________________                                    

As in Example 1, the TEOS and silane coupling agent were separately acid hydrolyzed before combination and addition of acrylate monomer, benzophenone photoinitiator and surfactant.

When coated and tested in comparison with the composition of Example 1, the acrylate composition gave stain and gloss protection better than a control, but not as good as an epoxy formulation. Results are shown in Table 3.

                  TABLE 3                                                          ______________________________________                                                                        90 Min.                                                          Stain         % Gloss                                         Sample           Resistance    Retained                                        ______________________________________                                         Control no coating                                                                              Severe        15%                                             Example 1 epoxy monomer                                                                         None          94%                                             Example 5 acrylate monomer                                                                      Moderate to None                                                                             74%                                             ______________________________________                                    

EXAMPLE 6

Coating compositions were prepared and tested as in Example 1 except using a surfactant selected from: Triton® X-100, Surfynol 104-E, Aerosol OT, FC-120, Tergitol NP-27. While a satisfactory wear surface was produced, these tests did not produce the superior stain and gloss protection of Examples 1 to 5 wherein a silicone surfactant was incorporated in the composition.

EXAMPLE 7

A coating composition was prepared and tested as in Example 1 except that a vinyl monomer, i.e. triethylene glycol divinyl ether, was substituted for the epoxy monomer. Fully equivalent wear and stain were obtained as illustrated in Tables 1 and 2.

EXAMPLE 8

Coating compositions were prepared and tested as in Example 1 except that portions of TEOS were replaced with triethylborate (TEB). Test samples were cured at 3 joules U.V. exposure. The coating compositions were examined over time to determine shelf life. Table 4 contains comparative results for stain and gloss retention.

                  TABLE 4                                                          ______________________________________                                                        Age of                % Gloss                                   TEOS   TEB     Formulation Dye Stain Retained                                  ______________________________________                                         (Control)  (Uncoated)  Severe      30                                          Example 1 -                                                                               7 days      Formulation                                                                    jelled                                                  99.75  0.25    7 days      Slight    99                                        99.5   0.5     7 days      Slight    98                                        99     1.0     7 days      Moderate  96                                        98.5   1.5     7 days      Moderate  97                                        ______________________________________                                     

What is claimed is:
 1. A polymer/glass hybrid coating consisting essentially of the reaction product of an acid-catalyzed hydrolysis product of a metal alkoxide selected from the group consisting of tetramethylorthosilicate, tetraethylorthosilicate and tetrapropylorthosilicate, and an acid-catalyzed hydrolysis product of a coupling agent having a metal alkoxide functionality and an organic functionality, the organic functionality of the coupling agent being selected from the group consisting of acrylic, methacrylic and epoxy moieties.
 2. The polymer/glass hybrid coating of claim 1, wherein the metal alkoxide functionality of the coupling agent is selected from the group consisting of aluminum alkoxide, zirconium alkoxide, silicon alkoxide and titanium alkoxide.
 3. The polymer/glass hybrid coating of claim 1, wherein the coupling agent is a trialkoxysilane.
 4. The polymer/glass hybrid coating of claim 1, wherein the coupling agent is a silane coupling agent.
 5. The polymer/glass hybrid coating of claim 4, wherein the silane coupling agent is an epoxy/silane.
 6. A polymer/glass hybrid coating comprising the reaction product of an acid-catalyzed hydrolysis product of a metal alkoxide, an acid-catalyzed hydrolysis product of a coupling agent having a metal alkoxide functionality and an organic functionality, and a multifunctional organic monomer, the organic functionality of the coupling agent being selected from the group consisting of acrylic, methacrylic and epoxy moieties, the multifunctional monomer having multiple acrylate or methacrylate groups when the coupling agent is an acrylate or methacrylate, the multifunctional monomer having multiple epoxide groups when the coupling agent is an epoxide, the polymer/glass hybrid coating being substantially free of colloidal silica.
 7. The polymer/glass hybrid coating of claim 6, wherein the coupling agent is a trialkoxysilane.
 8. The polymer/glass hybrid coating of claim 6, wherein the multifunctional monomer includes at least two cycloaliphatic epoxide functionalities.
 9. The polymer/glass hybrid coating of claim 6, wherein the coating comprises the reaction product of an acid-catalyzed hydrolysis product of a silicon alkoxide, an acid-catalyzed hydrolysis product of a silane coupling agent, and a multifunctional organic monomer.
 10. The polymer/glass hybrid coating of claim 9, wherein the coating comprises on a weight basis the reaction product of(a) about 10 to about 70 percent acid-catalyzed hydrolysis product of at least one silicate selected from the group consisting of tetramethylorthosilicate, tetraethylorthosilicate and tetrapropylorthosilicate; (b) about 1 to about 70 percent acid-catalyzed hydrolysis product of an epoxy/silane coupling agent; and (c) about 1 to about 70 percent diepoxide monomer having at least one cyclohexene oxide functionality.
 11. The polymer/glass hybrid coating of claim 10, wherein (b) is 3-glycidoxypropyltrimethoxysilane.
 12. The polymer/glass hybrid coating of claim 10, wherein (c) is 3,4-epoxycyclohexylmethyl-(3,4-epoxycyclohexane)carboxylate.
 13. The polymer/glass hybrid coating of claim 6, wherein the metal alkoxide is selected from the group consisting of tetramethylorthosilicate, tetraethylorthosilicate and tetrapropylorthosilicate.
 14. A polymer/glass hybrid coating consisting essentially of the reaction product of an acid-catalyzed hydrolysis product of a metal alkoxide, an acid-catalyzed hydrolysis product of a coupling agent having a metal alkoxide functionality and an organic functionality, and a multifunctional organic monomer, the organic functionality of the coupling agent and the organic functionality of the multifunctional monomer being reactively compatible, the organic functionality of the coupling agent being selected from the group consisting of acrylic, methacrylic and epoxy moieties. 